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Jewelry and Decoration (Electroplating)

Jewelry and Decorations
Precious Metal Compounds for Surface Coating and Plating
Metals can be deposited on surfaces in the form of thin layers. These serve various purposes (partly in combination), such as:
• Resistance to oxidation and corrosion
• Mechanical protection, due to hardness
• Optical attraction - luster
Such requirements are mainly found in the fields of jewelry.
Precious metals, mainly the platinum group metals (PGM's) platinum (Pt), palladium (Pd), rhodium (Rh), ruthenium (Ru), and the metals gold (Au), and silver (Ag), meet most of these requirements.
Electroplating in particular makes use of precious metal compounds by reducing the metal ions and depositing metals from aqueous solutions ("electrolytes") of compounds ("salts") in a micrometer range.
These electrolytes contain the metals in oxidized states. Reduction to the elements and deposition are only practicable either with a direct current flow ("Electroplating") or with chemical reducers ("Electroless Plating").
For electroplating, the parts to be metallized are submerged in the electrolytes as cathodes (reduction site). The anodes (oxidation site) are often made of platinized titanium or of the metal itself ("Sacrificial Anodes" of gold or silver, e.g. for cyanide baths). Depending on the types of the parts, the plating units use racks or barrels for holders.
Electroless plating is mainly suitable for workpieces of high complexity. The chemical reducer can be either a chemical compound (e.g. formaldehyde) or the non-noble workpiece itself.
For a better adhesion there is often need for an intermediate plating with base metals (e.g. nickel). And for specific physical requirements (color, hardness, etc.), the electrolytes themselves often contain further metals or additives.
Precious metal compounds serve to manufacture these plating electrolytes, but also to replenish just the metals that deposit from these electrolytes.


Our Chemical Products business unit manufactures suitable compounds and their solutions as core products, which serve for the production and the replenishing of plating electrolytes.
• Platinum (Pt)
Pt forms comparatively thick deposits, which show a decorative grey shade.

For plating with platinum, Heraeus manufactures important starting materials, e.g.:

• cis-Diamminedinitritoplatinum(II) solutions, cis-[Pt(NO2)2(NH3)2] (solutions of "Pt-P Salt")
• Tetraammineplatinum(II) chloride hydrate, [Pt(NH3)4]Cl2•nH2O
• Palladium (Pd)
For example, Pd can serve as an activator for top coats of base metals. Baths for electroless Pd plating are used, too.

Heraeus offers you for plating with palladium e.g.:

• Diamminedinitritopalladium(II) solution, [Pd(NO2)2(NH3)2] (solution of "Pd-P Salt")
• Tetraamminepalladium(II) chloride hydrate, [Pd(NH3)4]Cl2•nH2O
• Dihydrogen tetrachloropalladate(II) solution, H2[PdCl4]
• Diamminedichloropalladium(II), [PdCl2(NH3)2]
• Tetraamminepalladium(II) sulfate solution, [Pd(NH3)4]SO4
• Rhodium (Rh)
The very high white remission of Rh is useful for the plating of frames of spectacles and in jewelry.

Heraeus supplies you with chemicals and concentrates of rhodium electrolytes , e.g.:

• Rhodium(III) sulfate solution, Rh2(SO4)3
• Rhodium(III) phosphate solution, RhPO4
• Rhodium bath "DK20"
• Rhodium bath "RE"
• Rhodium bath "DK80"
• Ruthenium (Ru)
Layers of ruthenium are grey to blackish, and therefore are of interest to decorative applications.

Heraeus, your partner for coating with Ru compounds, e.g.:

• Ruthenium(III) chloride hydrate, RuCl3•nH2O
• Ammonium µ-nitrido-bis[aquatetrachlororuthenate(IV)], (NH4)3[{RuCl4(H2O)}2(µ-N)]
• Gold (Au)
represents the precious metal established in all the processes and branches mentioned above. There is a large number of electrolytes on the market, which meet the various requirements of gold plating (shade, hardness, adhesion, etc.).

Strongly acid electrolytes based on trivalent gold serve to electroplate e.g. high-grade steel. Most of the gold baths that are weakly acid or even neutral contain the monovalent metal, which is replenished in the form of "Gold Salt" [chemical term: potassium dicyanoaurate(I)]. The main fields for gold plating are jewels, cutlery, buttons, medals, etc.

Heraeus' starting materials for gold plating are e.g.:

• Hydrogen tetrachloroaurate(III) hydrate, H[AuCl4]•nH2O
• Potassium dicyanoaurate(I), K[Au(CN)2]
• Potassium tetracyanoaurate(III), K[Au(CN)4]
• Silver (Ag)
Ag is common for decorative purposes in form of plating baths on the basis of "Silver Salt" [chemical term: potassium dicyanoargentate(I)]. Electroless plating with silver(I) nitrate serves to produce mirror finish, e.g. for the manufacture of Christmas decorations or of Thermos bottles.

Heraeus offers you Ag chemicals for plating, e.g.:

• Potassium dicyanoargentate(I), K[Ag(CN)2]
• Silver(I) nitrate, AgNO3
• Silver(I) cyanide, AgCN
We look forward to your enquiries and are at your disposal at any time. Should you not find the product you are searching for, please feel free to contact us.
Our company also offers you the recovery of precious metals from e.g. spent electrolytes. For this, please, visit the web page of our Recycling business unit.